Population-Controlled Impulsive Vibrational Spectroscopy: Background- and Baseline-Free Raman Spectroscopy of Excited Electronic States
نویسندگان
چکیده
منابع مشابه
Background-free stimulated Raman spectroscopy and microscopy.
We propose a three-color, double-modulation scheme for the background-free detection of stimulated Raman scattering (SRS). We call the scheme stimulated Raman gain and opposite loss detection (SRGOLD). It exploits the symmetric nature of potential parasitic signals (cross phase modulation, two-photon absorption, and thermal effects) to the end of suppressing them. Conversely, the antisymmetric ...
متن کاملFilament-driven impulsive Raman spectroscopy.
Vibrational Raman spectroscopy is performed in the gas phase using a femtosecond laser pulse undergoing filamentation as an impulsive excitation source. The molecular coherence induced by the filamentary pulse is subsequently probed using a narrowband, sub-picosecond laser pulse to produce Raman spectra of gas phase species in a few tens of milliseconds (~10 laser shots). Pulse shortening with ...
متن کاملSpectroscopy of highly excited vibrational states of HCN in its ground electronic state.
An experimental technique based on a scheme of vibrationally mediated photodissociation has been developed and applied to the spectroscopic study of highly excited vibrational states in HCN, with energies between 29,000 and 30,000 cm(-1). The technique consists of four sequential steps: in the first one, a high power laser is used to vibrationally excite the sample to an intermediate state, typ...
متن کاملSurface-Enhanced Impulsive Coherent Vibrational Spectroscopy
Surface-enhanced Raman spectroscopy (SERS) has attracted a lot of attention in molecular sensing because of the remarkable ability of plasmonic metal nanostructures to enhance the weak Raman scattering process. On the other hand, coherent vibrational spectroscopy triggered by impulsive excitation using ultrafast laser pulses provides complete information about the temporal evolution of molecula...
متن کاملAccidental vibrational degeneracy in vibrational excited states observed with ultrafast two-dimensional IR vibrational echo spectroscopy.
The coupling between the OD stretch v=2 level and benzene-ring modes in 2-methoxyphenol-OD (hydroxyl H replaced by D) is observed with ultrafast two-dimensional (2D) IR vibrational echo spectroscopy. Because of this coupling, the 1-2 transition peak in the 2D spectrum is split into a doublet with peaks of approximately equal amplitudes. Several molecules and solvents were used to study this phe...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of Physical Chemistry A
سال: 2014
ISSN: 1089-5639,1520-5215
DOI: 10.1021/jp5075863